| Character | How to unlock
|
|---|
| - Defeated 90 strong enemies, performed 6 link attacks, and defeated Akainu with Ace 1 time.
|
| |
| - Win 2 fights with Sanji and any female character.
|
| - Clear 1 Boss Rush and Clear 3 Battle Royales with Luffy.
|
| |
| - Pull off 15 dodges with Hancock and trigger 5 item word effects.
|
| - Clear 5 Battle Royales and perform 1 link attack.
|
| - Pull off 6 counters with Zoro.
|
| - Cleared 3 scrambles with Doflamingo, defeated 25 bosses with Akainu, and performed 12 special attacks with Akainu.
|
|
| |
| - Perform 8 special attacks with Ace, Pull off 110 dodges with Ace, and perform 2 link attacks with Luffy and Ace.
|
| |
| |
| - Clear 2 battles with Nami.
|
| |
| - Defeated 20 bosses with Buggy, performed 2 link attacks with Buggy, and pulled off 25 dodges with Buggy.
|
| |
| |
| - Defeat 600 enemies with Shanks, Win 3 battles with Ace and Jimbei, and beat the battle coliseum.
|
