| Unlockable | How to Unlock
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| - Get 50 proficiency with Cao Cao, Liu Bei and Sun Quan.
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| - Get 50 proficiency with Nobunaga Oda, Hideyoshi Toyotomi and Ieyasu Tokugawa.
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| - Complete a total of 45 stages in Story or Dream Mode.
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| - Unlock the three characters involved.
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| - Clear stage 7 of Wei's Story.
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| - Unlock the three characters involved.
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| - Unlock the three characters involved.
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| - Unlock the three characters involved.
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| - Clear Wei's Story Mode and then unlock the three characters involved.
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| - Get level 99 with Zhang Liao, Gan Ning and Kotaro Fuuma.
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| - Get level 99 with Xiahou Yuan, Huang Zhong and Ina.
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| - Sum of all charaters' levels equals 1820 or above.
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| - Unlock the three characters involved.
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| - Unlock the three characters involved.
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| - Sum of all characters' levels equals 910 or above.
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| - Complete 30 stages in Story Mode.
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| - Sum of all characters' levels equals 3640 or above.
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| - Sum of all characters' proficiency levels equals 2730 or above.
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| - Clear the last stage of Orochi's Story.
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