Complete the indicated task to unlock the corresponding character in Player VS. COM mode.

Character	How to unlock
Material L (Dark Hayate)	Complete Story mode in vertical lane as Hayate Shamal and Reinforce.
Material M (Dark Fate)	Complete Story mode in vertical lane as Fate Signum and Chrono.
Material S (Starlight Destroyer)	Complete Story mode in vertical lane as Nanoha Vita and Zafila.