Akamaru: Complete 25 missions
Anko Mitarashi: complete 50 missions
Awakened Hinata: complete 100 missions
Haku: complete 40 missions
Iruka Umino: complete 15 missions
Itachi Uchiha: complete 55 missions
Kabuto Yakushi: get a S rank in strongest rival as Tsunade.
Crow: complete 35 missions
Kimimaro Kaguya: complete 30 missions
Mizuki: complete 20 missions
Kisame Hoshigaki: get a S rank in strongest rival as Might guy.
Nine Tail Naruto: get a S rank in strongest rival as Sasuke.
Orochimaru: complete 65 missions
Third Hokage: complete 85 missions
Sasuke(Cruse seal Lv.2): complete 120 missions
Tayuya: complete 10 missions
Kidomaru: complete 10 missions
Jirobo: complete 10 missions
Sakon: complete 10 missions
Ukon: complete 5 missions
Zabuza Momochi: complete 45 missions
Tayuya (Cruse seal Lv.2): complete 110 missions
Kidomaru (Cruse seal Lv.2): complete 150 missions
Jirobo (Cruse seal Lv.2): complete 105 missions
Sakon&Ukon (Cruse seal Lv.2): complete 100 missions
Kimimaro(Cruse seal Lv.2): complete 120 missions
Sharingan Kakashi: get a S rank in strongest rival as Zabuza.
Orochimaru (Sealed arms): unlock Kabuto&Orocimaru.
Sasuke (Old outfit): complete 200 missions