Successfully complete the indicated Story mode chapter to unlock the corresponding movie:

Atlantis: Four Adventures Of The Sea Special Edition: V-Puzzle 6
Atlantis: Four Adventures Of The Sea: Gulliver's Battles
Boss*Boss*Bang*Bang: All previous chapters except The Hidden Hideout
Ending Movie: Les Acteurs Incroyable
Captain Blue Begins: Viewtiful Cartoon World
Captain Blue Begins Special Edition: V-Puzzle 3
Gulliver's Battles: Truth Of The Black Film
Gulliver's Battles Special Edition: V-Puzzle 5
Les Acteurs Incroyable: Atlantis: Four Adventures Of The Sea
Red Hot Rumble: Boss*Boss*Bang*Bang
Riddle Of The Incan Empire! Special Edition: V-Puzzle 1
The Hidden Hideout: Any chapter with Charles The Third, Hulk Davidson, and Gran Bruce
Truth Of The Black Film: Captain Blue Begins
Truth Of The Black Film Special Edition: V-Puzzle 4
Viewtiful Cartoon World Special Edition: V-Puzzle 2
Viewtiful Cartoon World: Riddle Of The Incan Empire!
Opening Movie: Riddle Of The Incan Empire!
Last Battle Intro Movie: Les Acteurs Incroyable