Get your special meter (meter underneath the Superstar's name) full, then do the following:

Booker T's Book-End: Grapple your opponent and press Select.

Booker T's Scissors Kick: Grapple your opponent and press Select.

Booker T's Scissors Kick: Kick on your opponent, then press Select.

Chavo Guererro's (Unknown name): Grapple your opponent and press Select.

Chavo Guererro's Frog Splash: Climb to the top rope and press Select.

Chris Benoit's Crippler Crossface: Put your opponent on his stomach, then go to the head and press Select.

Chris Benoit's Diving Headbutt: Climb to the top rope and press Select. Note: Make sure your opponent is in range.

Chris Benoit's Rolling German Suplexs: Grapple your opponent from behind and press Select.

Chris Jericho's The Walls of Jericho: Put your opponent on his back, then go to feet and press Select.

Chris Jericho's German Suplex: Grapple your opponent from behind and press Select.

Christian's Unprettier: Grapple your opponent from behind and press Select.

Eddie Guererro's Frog Splash: Climb to the top rope and press Select. Note: Make sure your opponent is in range.

Eddie Guererro's Three Amigos: Grapple your opponent and press Select.

Edge's Edgecution: Grapple your opponent and press Select.

John Cena's F-U: Grapple your opponent(does not have to be stunned) and press Select.

Kane's Chokeslam: Grapple your opponent and press Select.

Kurt Angle's Angle Slam: Grapple your opponent and press Select.

Kurt Angle's Ankle Lock: Put your opponent on his stomach, then go to the feet and press Select.

Kurt Angle's Rolling German Suplexes: Grapple your opponent from behind and press Select.

Randy Orton's RKO: Grapple your opponent and press Select.

Randy Orton's Running RKO: Run to your opponent and press Select.

Rey Mysterio's 619: Get your special bar filled, then press Select while in front of your opponent.

Rey Mysterio's Bulldog: Grapple your opponent and press Select.

Rey Mysterio's Running Bulldog: Run to your opponent and press Select.

Rob Van Dam's 5 Star Frog Splash: Climb to the top rope and press Select. Note: Make sure your opponent is in range.

Rob Van Dam's Van Daminator: Grapple your opponent and press Select.

Shawn Micheals' Sweet Chin Music: Press Select.

The Undertaker's Tombsstone: Grapple your opponent and press Select.

The Undertaker's Tombstone Piledriver: Grapple your opponent and press Select.

The Undertaker's Last Ride: Kick on your opponent, then press Select.

Triple H's Pedigree: Grapple your opponent and press Select.

Super Suplex: Pull your opponent (grapple him, then press R + Left or Right ) to a corner. Then, grapple him and press Up.