Unlockable - How to Unlock

Aizen Sousuke - Clear Arcade Mode with Ulquiorra
Arturo Plateado - Unknown; in relation to Story Mode
Grimmjow Jaggerjack - Clear Arcade Mode with Aizen Sousuke
Hinamori Momo - Unknown; in relation to Story Mode
Hisagi Shuuhei - Unknown; in relation to Story Mode
Ichimaru Gin - Clear Arcade Mode with Matsumoto Rangiku
Kuchiki Rukia - Unknown; in relation to Story Mode
Kurotsuchi Mayuri - Clear Arcade Mode with Ishida Uryuu
Kusajishi Yachiru - Clear Arcade Mode with Yumichika Ayasegawa
Kyouraku Shunsui - Clear Arcade Mode with Sado Yasutora
Madarame Ikkaku - Unknown; in relation to Story Mode
Shihouin Yoruichi - Clear Training Mode
Soi Fon - Unknown; in relation to Story Mode
Tousen Kaname - Clear Arcade Mode with Komamura Sajin
Ukitake Juushiro - Clear Arcade Mode with Kyouraku Shunsui
Ulquiorra - Clear Arcade Mode with Ichimaru Gin
Urahara Kisuke - Clear Arcade Mode with Kurotsuchi Mayuri
Yamada Hanatarou - Unknown; in relation to Story Mode
Yamamoto Genryuusai Shigekuni - Clear Arcade Mode with Ukitake Juushiro
Yumichika Ayasegawa - Clear Arcade Mode with Madarame Ikkaku