| Achievement | How to unlock
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| - Public Match: Reach level 50 (00 Agent Grade 0).
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| - Complete all levels on a 'Classic' difficulty.
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| - Multiplayer: Enter 00 Specialization.
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| - Complete three of the '007' level trials.
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| - Earn a 3 star rating in any mission of the Challenges mode.
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- All the Time in the World
| - Public Match: Play for more than 24 hours.
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- Around the world one more time
| - Get 100% collection rating for 'Moonraker'.
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| - Campaign: Buy all of the attachments for one weapon class.
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| - Earn a 1 star rating in each mission of the Challenges mode.
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| - Campaign: Collect 100% of all organization intel.
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| - Public Match: Kill 50 players while they are aiming down the scope of a sniper rifle.
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| - Public Match: Get 25 electrocution kills as Zao or Gustav Graves.
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| - Complete the 'Die Another Day' mission.
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| - Public Match: In Escalation demote an enemy who is armed with the RPG.
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| - Complete all of the trials on any one level.
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| - Complete eight of the 'Operative' level trials.
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- Fascination with all things gold
| - Get 100% of all available stars in the Challenges mode.
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| - Complete the 'Goldfinger' mission.
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| - Campaign: Take a photograph of the crocodile.
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| - Public Match: Win a Data Miner match without being killed.
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| - Get 100% collection rating for 'Goldfinger'.
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| - Public Match: Win a match using only laser-based weapons.
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| - Complete the 'Licence To Kill' mission.
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| - Campaign: Collect 100% of all character bio intel.
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| - Make an elimination with every weapon class.
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| - Public Match: Win a match on Main Vault, Smelting Room and Loading Bay.
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| - Complete the 'Moonraker' mission.
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| - Complete six of the 'Agent' level trials.
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- Never happened to the other guy
| - Get 100% collection rating for 'O.H.M.S.S.'
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| - Complete the 'O.H.M.S.S.' mission.
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| - Public Match: Kill an enemy who has completed the campaign or who already has this Achievement.
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| - Campaign: Collect 30% of all character bio intel.
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| - Take out two enemies with one shock dart.
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| - Public Match: In Bomb Defuse disarm the bomb and plant it at enemy base without getting killed.
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- Scream if you want to go faster
| - Campaign: Overload the gyroscopic training machine in the Space Port.
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| - Complete all levels on 'Agent' difficulty or higher.
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| - Public Match: Survive 50 explosions while using Reactive Armor.
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| - Get 30% of all available stars in the Challenges mode.
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| - Campaign: Reach level three weapon proficiency with the P99.
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- Spend the money quickly Mr. Bond
| - Campaign: Be awarded a total of 10,000 XP.
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- Standards of Physical Perfection
| - Campaign: Acquire all of the MI6 training modules.
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| - Get 60% of all available stars in the Challenges mode.
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| - Public Match: Reach level 6 (Midshipman).
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| - Campaign: Upgrade a gadget to its highest level.
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- Vodka martini, plenty of ice...
| - Get 100% collection rating for 'Die Another Day'.
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| - Campaign: Collect 30% of all organization intel.
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| - Reach Grave's plane without using any in-car gadgets.
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- You prepare for the unexpected
| - Get 100% collection rating for 'Licence To Kill'.
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