| Achievement | How to unlock
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| - Construct the Great Firewall Wonder.
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- All Your Barbarians Are Belong To Us
| - Capture and recruit all the barbarian Unique Units using Western Roman Legions without any of them dying in the Fall of Rome scenario.
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| - As the Maya, nuke a city in the year 2012.
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| - Beat the game on any difficulty as Maria Theresa.
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| - Beat the game on any difficulty as Pacal
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| - Capture a Spanish Coastal City with a Dutch Sea Beggar.
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| - Beat the game on any difficulty as Boudicca
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| - Beat the game on any difficulty as Haile Selassie
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- Dancer, Actress, Empress, Victor
| - Beat the game on any difficulty as Empress Theodora
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| - Beat the game on any difficulty as Gustavus Adolphus.
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| - Capture both Rome and Constantinople in the same game in the Fall of Rome scenario.
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| - Win the Fall of Rome scenario.
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| - As Russia, kill an English Spy
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| - Share intrigue with another player in the Empires of the Smokey Skies scenario.
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| - Bully 3000 gold from City-States across any number of playthroughs.
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| - As Byzantines, sink 10 Greek ships with a Dromon
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| - As Carthage, attack a Roman Unit with an African Forest Elephant from a mountain tile.
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| - Become the dominant Religion in an opponent's Holy City.
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| - Select the Papal Primacy Belief and Ally with 12 City-States.
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- I Missed That Day in History Class
| - Capture any Sassanid city as the Celts in the Fall of Rome scenario.
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- I Sunk Your Imperial Capital!
| - Capture Rome as the Vandals using a boat in the Fall of Rome scenario.
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| - Lose dominant status in your Holy City to an opponent's Religion.
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| - Share intrigue with a player who previously shared intrigue with you.
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| - Use a Spy to successfully stage a City-State coup
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| - As Sweden, start a turn with your Great General stacked with a Hakkapelitta.
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| - Have the city of Llanfairpwllgwyngyll in your empire.
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| - As the Turks, conquer Istanbul on Deity in the Into the Renaissance scenario.
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| - Spread your Religion to an opponent with a Missionary.
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| - Win the Empires of the Smoky Skies scenario
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| - Win as the Celts on Emperor or above in the Into the Renaissance scenario.
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| - Beat the game on any difficulty as Dido
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| - As Spain, use an Inquisitor to remove another Religion.
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| - Win the game as Eastern or Western Rome on Deity and have all your original cities under your control in the Fall of Rome scenario.
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| - Retain control of the same honourable title for the entire length of the game it is available in the Empires of the Smokey Skies scenario
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| - Research Satellites while playing as Attila on a huge map.
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| - As Ethiopia, earn 5 Great Prophets
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| - Win as the Almohads on Emperor or above in the Into the Renaissance scenario.
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| - Win the Into the Renaissance scenario.
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| - As England, conquer Jerusalem on Emperor or above in the Into the Renaissance scenario.
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| - Beat the game on any difficulty as Attila.
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| - Beat the game on any difficulty as William of Orange
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| - Destroy an enemy unit with a Flyer based at a Sky Fortress in the Empires of the Smoky Skies scenario.
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| - Use a Spy to gain influence with a City-State
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| - Use a spy to steal Technology from a competitor
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| - Capture the city that built Petra using a Landship
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| - Win as Russia on Emperor or above in the Into the Renaissance scenario.
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| - Capture Constantinople as any enemy power in the Fall of Rome scenario.
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| - Become the dominant Religion in every Capital city on a standard-size or larger map.
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| - Find and kill an enemy Spy.
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| - As Austria, replace another civ as allies with a City-State and acquire the City-State through diplomatic marriage in the same turn
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