Use the following moves with the indicated player in a Five vs. Five or One vs. One game. They cannot be done in Practice mode.

Allen Iverson: Back down your opponent then lean towards the basket with a shot.
Chris Bosh: Back down your opponent then fadeaway from the basket with a shot.
Chris Paul: Back down your opponent then lean towards the basket with a shot.
Dirk Nowitzki: Back down your opponent then fadeaway from the basket with a shot.
Dwayne Wade: Back down your opponent then fadeaway from the basket with a shot.
Elton Brand: Back down your opponent then fadeaway from the basket with a shot.
Gilbert Arenas: Back down your opponent then fadeaway from the basket with a shot.
Kobe Bryant: Back down your opponent then fadeaway from the basket with a shot.
Lebron James: Use any fadeaway shot near the 3 point line.
Steve Nash: Back down your opponent then lean towards the basket with a shot.
Tim Duncan: Use a bank shot at about a 45 degree angle to the basket.
Tony Parker: Use a tear drop shot in the lane and lean towards the basket.
Tracy McGrady: Back down your opponent then fadeaway from the basket with a shot.
Vince Carter: Back down your opponent then fadeaway from the basket with a shot.