The following moves can be learned from the indicated Mentor. Note: The fourth move for each character is an Ultimate attack.

Move	How to unlock
Android #18	Power Blitz, Endless Shoot, Deadly Dance, Dual Destructo-disc.
Beerus	Headshot, (nothing), God of Destruction's Anger, Sphere of Destruction.
Cell	All Clear, Gravity Impact, Perfect Shot, Perfect Kamehameha.
Frieza	Death Beam, Death Crasher, Emperor's Sign, Supernova Ghost Kamikaze Attack (Ultimate).
Ginyu	Fighting Pose F, Fighting Pose A, Milky Cannon, Body Change (1v1 only Ultimate).
Gohan and Videl	Eagle Kick, Hawk Charge, Ki Blast Combination, Justice Combination.
Goku	Afterimage Stirke, Spirit Bomb, Kamehameha X10 and Super Kamehameha.
Gotenks	Galactic Donuts, DIE DIE Missile Barrage, Super Ghost Kamikaze Attack (Super), Super.
Hercule	Rolling Hercule Punch, Dynamite Kick, Present for You, Savior Has Arrived.
Krillin	Orin Combo, Destructo Disc, Spread Shot Retreat (Evasive), Scatter Kamehameha.
Piccolo	Evil Explosion, Super Explosive Wave (Evasive), Light Grenade, Special Beam Cannon.
Vegeta	Galick Gun, Finish Breaker, Shine Shot, Final Flash.