Defeating Rhino
When Rhino tries to hit you, there will be a flash above Spider-Man's head. Press B when this happens. When Rhino stops spinning, he will be dizzy. Punch him until he recovers, then he will charge at you. Jump over him. Do not punch or web him. If you web him you will get hurt. If you punch him it will not have any affect because there is metal around his body.