Defeat Arturo Plateado on the final stage of episode mode.
Arturo Plateado
Clear Episode Mode with Arturo Plateado.
Continuous special attack
When you use your Bankai's special attack, if keep shaking the Wiimote and Nunchuk. The special attack can continue up to three times.
After using a special attack, keep shaking the Wiimote to increase the damage and hits. For Ikkaku's Bankai, the dragon charge meter will get full. Because Byakuya has two special attacks, this trick only works for Shuukei Hakuteiken, decreasing the cast time from five to two seconds.
Grimmjow Jaggerjack
Clear Arcade Mode with Aizen Sousuke.
Hanataro Yamada's Episode: Easy completion
When fighting enemies in Hanataro's Episode, hit your enemy once or twice and keep away from them. Make sure your opponent has more damage than yourself. If you successfully make it through the time limit with less damage than your opponent, you will automatically win. Because Hanataro is a weak character, this can be a vital strategy.
Hinamori Momo
Clear Hitsugaya Toushiro's story.
Hisagi Shuuhei
Clear Episode Mode with Yamada Hanatarou.
Hitsugaya School Costume
Win 15 matches with Toushiro Hitsugaya.
Ice Haven
Complete Hitsugaya's episode mode.
Ichimaru Gin
Clear Arcade Mode with Matsumoto Rangiku and Kira Izuru.
Ikkaku School Costume
Win 10 matches with Madarame Ikkaku.
Kisuke
To get Kisuke, defeat Mayrui in arcade mode.
Kuchiki Rukia
Beat Story mode with Abarai Renji.
Kurotsuchi Mayuri
Clear Arcade Mode with Ishida Uryuu.
Kusajishi Yachiru
Clear Arcade Mode with Yumichika Ayasegawa and Zaraki Kenpachi.
Kyouraku Shunsui
Clear Arcade Mode with Sado Yasutora.
Madarame Ikkaku
Clear Episode Mode with Zaraki Kenpachi.
Masked Komamura Costume
Win 15 matches with Komamura Sajin.
Matsumoto School Costume
After unlocking Inoue Orihime's costume, win 15 matches with Matsumoto Rangiku.
Mayuri Kurosuchi
To unlock Mayuri Kurotsuchi for your use, defeat Uryu Ishida in Arcade Mode.
Old Man Yama
To unlock Old Man Yama as a playable character, you must beat Arcade Mode with Rukias Capton.
Orihime School Costume
Win 15 matches with Inoue Orihime.
Renji School Costume
Win 15 matches with Abarai Renji.
Rukia School Costume
Win 15 matches with Kuchiki Rukia.
Shihouin Yoruichi
Clear Training Mode.
Shihouin Yoruichi Shunpo Costume
After completing practice mode, win 15 matches with Yoruichi.
Soi Fon
Clear Episode Mode with Shihouin Yoruichi.
Tousen Kaname
Clear Arcade Mode with Komamura Sajin.
Treasure Box
Unlock all characters to unlock the Treasure Box will appear in the shop. It contains an art gallery of images from the game.
Ukitake Juushiro
Clear Arcade Mode with Kyouraku Shunsui.
Ulquiorra
Clear Arcade Mode with Ichimaru Gin.
Uniforms
To unlock most alternate uniforms/outfits in the game, you must first unlock the character in question and then win fifteen battles in Versus Mode as that character.
Urahara Kisuke
Clear Arcade Mode with Kurotsuchi Mayuri.
Urahara Kisuke Shinigami Costume
Unlock everything, It becomes available for free in Urahara's Shop.
Yamada Hanatarou
Beat Story Mode with Youshiro Hitsugaya.
Yamamoto Genryuusai Shigekuni
Clear Arcade Mode with Ukitake Juushiro.
Yoruchi
To play as Yoruchi, simply complete Tutorial Mode.